Carbon monoxide is a very important industrial compound. In the form of producer gas or water gas, it is widely used as a fuel in industrial operations. The gas is also an effective reducing agent. For example, when carbon monoxide is passed over hot iron oxides, the oxides are reduced to metallic iron, while the carbon monoxide is oxidized to carbon dioxide.
In another application a mixture of metallic ores is heated to 122–176°F (50–80°C) in the presence of producer gas. All oxides except those of nickel are reduced to their metallic state. This process, known as the Mond process, is a way of separating nickel from other metals with which it commonly occurs.
Yet another use of the gas is in the Fischer-Tropsch process for the manufacture of hydrocarbons and their oxygen derivatives from a combination of hydrogen and carbon monoxide. Carbon monoxide also reacts with certain metals, especially iron, cobalt, and nickel, to form compounds known as carbonyls. Some of the carbonyls have unusual physical and chemical properties that make them useful in industry. The highly toxic nickel tetracarbonyl, for example, is used to produce very pure nickel coatings and powders.
See also Metallurgy.
David E. Newton
Boikess, Robert S., and Edward Edelson. Chemical Principles. 2nd edition. New York: Harper & Row Publishers, 1981, pp. 672 - 673.
Brown, Theodore L., and H. Eugene LeMay Jr. Chemistry: The Central Science. 3rd edition. Englewood Cliffs, NJ: Prentice-Hall, 1985, pp. 390-392, 66 -669.
Budavari, Susan, ed. The Merck Index. 11th edition. Rahway, NJ: Merck and Company, 1989, pp. 1821.
Greenwood, N. N., and A. Earnshaw. Chemistry of the Elements. Oxford: Butterworth-Heinneman Press, 1997.
Lide, D.R., ed. CRC Handbook of Chemistry and Physics. Boca Raton: CRC Press, 2001.
Matthews, John A., E.M. Bridges, and Christopher J. Caseldine The Encyclopaedic Dictionary of Environmental Change. New York: Edward Arnold, 2001.
Partington, J.R. A Short History of Chemistry. 3rd edition. London: Macmillan & Company, 1957, pp. 49, 116, 142, 151.
The United Nations. "The Conference and Kyoto Protocol." (March 2003). <http://unfccc.int/resource/convkp.html>.