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Thermodynamics

The Second Law Of Thermodynamics



One of the most remarkable facts of nature is that certain processes take place in only one direction. For example, if a high temperature object is placed in contact with one of lower temperature, heat flows from the hotter to the cooler until the temperatures become equal. In this case (where there is no work done), the first law simply requires that the energy lost by one object should be equal to that gained by the other object (through the mechanism of heat flow), but does not prescribe the direction of the energy flow. Yet, in a situation like this, heat never flows from the cooler to the hotter object. Similarly, when a drop of ink is placed in a glass of water which is then stirred, the ink distributes itself throughout the water. Yet no amount of stirring will make the uniformly-distributed ink go back into a single drop. An open bottle of perfume placed in the corner of a room will soon fill the room with its scent, yet a room filled with perfume scent will never become scentfree with the perfume having gone back into the bottle. These are all examples of the second law of thermodynamics, which is usually stated in two different ways. Although the two statements appear quite different, it can be shown that they are equivalent and that each one implies the other.



Additional topics

Science EncyclopediaScience & Philosophy: Thallophyta to ToxicologyThermodynamics - Historical Background, Temperature, Expansion Coefficients, Thermostats, Water, Heat, The First Law Of Thermodynamics - Conservation of energy