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Thermodynamics - Equations Of State; Work

system object thermal found

When an object of interest (usually called the system) is left alone for a sufficiently long time, and is subject to no outside influences from the surroundings, measurements of the properties of the object do not change

TABLE 1. THERMODYNAMICS
Material Melting Point °C Heat of Fusion cal/gm Boiling Point °C Heat of Vaporization cal/gm
Water 0 79.7 100 539
Ethyl alcohol -114 24.9 78 204
Oxygen -219 3.3 -183 51
Nitrogen -210 6.1 -196 48
Mercury -39 2.8 357 65

with time; it is in a state of thermal equilibrium. It is found experimentally that there are certain measurable quantities that give complete information about the state of the system in thermal equilibrium (this is similar to the idea that measurements of the velocity and acceleration of an object give complete information about the mechanical state of a system). For each such state relationships can be found which hold true over a wide range of values of the quantities. These relationships are known as equations of state.


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