Flame Analysis - Analysis Of Emission Spectra, Qualitative Testing
bunsen techniques spectroscopy elements
Allowing analysis of the light (photons) from excited atoms, flame analysis is a form of atomic emission spectroscopy (AES).
German chemist Robert Bunsen's (1811–1999) invention of the Bunsen burner—a tool now commonly used in modern chemistry laboratories—also spurred the development of flame analysis. Working with Gustav Kirchhoff (1824–1887), Bunsen helped to establish the principles and techniques of spectroscopy. Bunsen's techniques also enabled his discovery of the elements cesium and rubidium.
Bunsen's fundamental observation that flamed elements emit light only at specific wavelengths, and that every element produced a characteristic spectra, paved the way for the subsequent development of quantum theory by German physicist Maxwell Planck (1858–1947), Danish physicist Niels Bohr (1885–1962), and others. Using techniques pioneered by Bunsen, scientists have since been able to determine the chemical composition of a variety of substances ranging from bioorganic debris to the composition of the stars.
Additional Topics
Bunsen examined the spectra; the colors of light emitted when a substance was subjected to intense flame. When air is admitted at the base of a Bunsen burner it mixes with hydrocarbon gas to produce a very hot flame at approximately 3,272°F (1,800°C). This temperature is sufficient to cause the emission of light from certain elements. Often termed "spectral fingerprints,…
Flame analysis is a qualitative test, not a quantitative test. A qualitative chemical analysis is designed to identify the components of a substance or mixture. Quantitative tests measure the amounts or proportions of the components in a reaction or substance. The unknown sample subjected to flame analysis is either sprayed into the flame or placed on a thin wire that is then introduced into the f…
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10 months ago
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