Electrical Conductivity - History, Metals, Semiconductors, Non-ohmic Conductors - Materials
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Conductivity is the term used to describe the ability of a material medium to permit the passage of particles or energy. Electrical conductivity refers to the movement of charged particles through matter. Thermal conductivity refers to the transmission of heat energy through matter. Together, these are the most significant examples of a broader classification of phenomena known as transport processes. In metals, electrical conductivity and thermal conductivity are related since both involve aspects of electron motion.
Electrical conduction can take place in a variety of substances. The most familiar conducting substances are metals, in which the outermost electrons of the atoms can move easily in the interatomic spaces. Other conducting materials include semiconductors, electrolytes, and ionized gases, which are discussed later in this article.
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The early studies of electrical conduction in metals were done in the eighteenth and early nineteenth centuries. Benjamin Franklin (1706-1790) in his experiments with lightning (leading to his invention of the lightning rod), reasoned that the charge would travel along the metallic rod. Alessandro Volta (1745-1827) derived the concept of electrical potential from his studies of static electricity,…
Metals are now known to be primarily elements characterized by atoms in which the outermost orbital shell has very few electrons with corresponding values of energy. The highest conductivity occurs in metals with only one electron occupying a state in that shell. Silver, copper, and gold are examples of high-conductivity metals. Metals are found mainly toward the left side of the periodic table of…
Semiconductors are materials in which the conductivity is much lower than for metals, and widely variable through control of their composition. These substances are now known to be poor insulators rather than poor conductors, in terms of their atomic structure. Though some semiconducting substances had been identified and studied by the latter half of the nineteenth century, their properties could…
Non-ohmic conduction is marked by nonlinear graphs of current vs. voltage. It occurs in semiconductor junctions, electrolytic solutions, some ionic solids not in solution, ionized gases, and vacuum tubes. Respective examples include semiconductor p-n diodes, battery acid or alkaline solutions, alkali halide crystals, the ionized mercury vapor in a fluorescent lamp, and cathode ray tubes. Ionic con…
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